Spider-Woman: Secrets and Lies

Brian Michael Bendis, the Luna Brothers and Alex Maleev
with Brian Reed and Frank Cho

NOTE: Spider-Woman was a key character during Brian Michael Bendis' initial New Avengers series and the reason why becomes clear as the series unfolds. (To avoid spoilers, I won't elaborate much beyond that). Spider-Woman was also featured in a number of one-shots and mini-series that occurred during the course of those Avengers appearances. I'll link to the Avengers series below and highlight spotlight issues or other solo issues in relation to their appearances.

Avengers: New Avengers

Giant-Size Spider-Woman #1
New Avengers #14
New Avengers #15

Origin
Spider-Woman: Origin #1
Spider-Woman: Origin #2
Spider-Woman: Origin #3
Spider-Woman: Origin #4
Spider-Woman: Origin #5

New Avengers #23

Avengers: Mighty Avengers
See: Revolution, Venom Bomb and Secret Invasion (including Mighty Avengers #12 & New Avengers #40, #42, #45)

Avengers: Dark Avengers

Astonishing Tales: Spider-Woman #1

Agent of S.W.O.R.D.
Spider-Woman #1
Spider-Woman #2
Spider-Woman #3
Spider-Woman #4
Spider-Woman #5
Spider-Woman #6
Spider-Woman #7